Abstract

Theoretical modelling of challenging multiscale problems arising in complex (and sometimes bioinspired) solids are presented. Such activities are supported by analytical, numerical and experimental studies. For instance, this is the case for studying the response of hierarchical and nano-composites, nanostructured solid/semi-fluid membranes, polymeric nanocomposites, to electromagnetic, mechanical, thermal, and sometimes biological, electrical, and chemical agents. Such actions are notoriously important for sensors, polymeric films, artificial muscles, cell membranes, metamaterials, hierarchical composite interfaces and other novel class of materials. The main purpose of this project is to make significant advancements in the study of such composites, with a focus on the electromagnetic and mechanical performances of the mentioned structures, with particular regards to novel concept devices for sensing. These latter ones have been studied with different configuration, from 3D colloidal to 2D quasi-hemispherical micro voids elastomeric grating as strain sensors. Exhibited time-rate dependent behavior and structural phenomena induced by the nano/micro-structure and their adaptation to the applied actions, have been explored. Such, and similar, ordered submicroscopic systems undergoing thermal and mechanical stimuli often exhibit an anomalous response. Indeed, they neither follow Fourier’s law for heat transport nor their mechanical time-dependent behavior exhibiting classical hereditariness. Such features are known both for natural and artificial materials, such as bone, lipid membranes, metallic and polymeric “spongy” composites (like foams) and many others. Strong efforts have been made in the last years to scale-up the thermal, mechanical and micro-fluidic properties of such solids, to the extent of understanding their effective bulk and interface features. The analysis of the physical grounds highlighted above has led to findings that allow the describing of those materials’ effective characteristics through their fractional-order response. Fractional-order frameworks have also been employed in analyzing heat transfer to the extent of generalizing the classical Fourier and Cattaneo transport equations and also for studying consolidation phenomenon. Overall, the research outcomes have fulfilled all the research objectives of this thesis thanks to the strong interconnection between several disciplines, ranging from mechanics to physics, from structural health monitoring to chemistry, both from an analytical and numerical point of view to the experimental one.